Synergistic effect of fluorinated hexane as diluent of fluorinated octanol for salicylic acid extraction

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dc.contributor.authorWu, Xue
dc.contributor.authorChang, Zhidong
dc.contributor.authorYuan, Junchao
dc.contributor.authorFeng, Jingge
dc.contributor.authorUslu, Hasan
dc.contributor.authorLi, Wenjun
dc.date.accessioned2025-03-26T17:35:09Z
dc.date.available2025-03-26T17:35:09Z
dc.date.issued2018
dc.departmentİstanbul Esenyurt Üniversitesi
dc.description.abstractIn order to get optimal extraction performance as well as ultra-low solvent residual, three fluorinated hexane, perfluorohexane (C6F14), 1H-perfluorohexane (C6F13H) and 1H,6H-perfluorohexane (C6F12H2), were evaluated as diluents for synergistic effect on extraction capability of 1H,1H,2H,2H-Perfluorooctan-1-ol by the way of experimental and computational investigation. Based on extraction experiments, C6F14 showed obvious antagonistic effect because of hydrophobic nature, while the synergistic effect of C6F12H2 was better than that of C6F13H. According to DFT calculation, supported by FT-IR and H-1 NMR spectra, the synergistic effect was illustrated as that fluorinated hexane could interact with salicylic acid-fluorinated octanol complex through hydrogen bond. (C) 2017 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
dc.description.sponsorshipNational Natural Science Foundation of China [21276022]
dc.description.sponsorshipThis work was financially supported by the National Natural Science Foundation of China (No. 21276022).
dc.identifier.doi10.1016/j.jiec.2017.09.042
dc.identifier.endpage318
dc.identifier.issn1226-086X
dc.identifier.issn1876-794X
dc.identifier.scopus2-s2.0-85030834870
dc.identifier.scopusqualityQ1
dc.identifier.startpage311
dc.identifier.urihttps://doi.org/10.1016/j.jiec.2017.09.042
dc.identifier.urihttps://hdl.handle.net/20.500.14704/1072
dc.identifier.volume58
dc.identifier.wosWOS:000424182500040
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Inc
dc.relation.ispartofJournal of Industrial and Engineering Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250326
dc.subjectFluorinated; Diluents; Solvent extraction; Synergistic effect; Hydrogen bond
dc.titleSynergistic effect of fluorinated hexane as diluent of fluorinated octanol for salicylic acid extraction
dc.typeArticle

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