Influence of fluorinated extractant aggregation in diluent on extraction of salicylic acid: Evidence from equilibrium, SAXS and molecular dynamics simulation

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dc.contributor.authorWu, Xue
dc.contributor.authorChang, Zhidong
dc.contributor.authorFeng, Jingge
dc.contributor.authorDang, Hui
dc.contributor.authorUslu, Hasan
dc.contributor.authorLi, Wenjun
dc.date.accessioned2025-03-26T17:35:09Z
dc.date.available2025-03-26T17:35:09Z
dc.date.issued2018
dc.departmentİstanbul Esenyurt Üniversitesi
dc.description.abstractIn order to get optimal extraction performance as well as ultra-low solvent residual, the extraction behavior of tris(2,2,3,3,4,4,4-heptafluorobutyl) phosphate (FTBP) dissolved in 2,3,4,5,6-Pentafluorotoluene (FB) was evaluated to investigate the influence of the aggregation state on the extraction of salicylic acid (SA). The effect of SA distribution and water content on aggregation structure in organic phase was assessed through analysis of SAXS data. Based on molecular dynamic simulation, FTBP tended to aggregate with the existence of FB to accommdate more SA molcules. Water in this case was not the critical factor for aggregation formation due to the hydrophobicity of fluorinated solvents. (C) 2018 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
dc.description.sponsorshipNational Natural Science Foundation of China [21276022]
dc.description.sponsorshipThis work was financially supported by the National Natural Science Foundation of China (No. 21276022).
dc.identifier.doi10.1016/j.jiec.2018.05.026
dc.identifier.endpage175
dc.identifier.issn1226-086X
dc.identifier.issn1876-794X
dc.identifier.scopus2-s2.0-85047559472
dc.identifier.scopusqualityQ1
dc.identifier.startpage168
dc.identifier.urihttps://doi.org/10.1016/j.jiec.2018.05.026
dc.identifier.urihttps://hdl.handle.net/20.500.14704/1071
dc.identifier.volume66
dc.identifier.wosWOS:000446144400015
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Inc
dc.relation.ispartofJournal of Industrial and Engineering Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250326
dc.subjectFluorinated; Solvent extraction; Aggregation; Hydrophobicity; Molecular dynamics
dc.titleInfluence of fluorinated extractant aggregation in diluent on extraction of salicylic acid: Evidence from equilibrium, SAXS and molecular dynamics simulation
dc.typeArticle

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